There is not much to specify for the question, its really simple: Which title is the first game you have purchased on Steam? Was it a good decision? How much did you pay? When was it and what device? You don’t have to answer all questions, this is just a fun discussion to have.
You can check your history: https://store.steampowered.com/account/history/ Edit: Some in the comments pointed out that the purchase history doesn’t go back all to the beginnings of Steam. So if you purchased something earlier, it won’t be listed on your account.
(I reply with my game too.)
HL2: Episode One, in August 2006. My Steam account was actually created in August 2004, that was just the first time I gave them a credit card number. Probably the first time I actually had a credit card number to give them!